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Which thermodynamic quantity always increases in an isolated system?

  • Entropy
  • Enthalpy
  • Free energy

The answer is Entropy. The second law.

Entropy

Entropy is a thermodynamic state variable that quantifies the probabilistic distribution of accessible microstates in a system. The term and the concept are used in diverse fields, from classical thermodynamics, to the microscopic description of nature in statistical physics, and the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, and information systems including the transmission of information in telecommunication.

Wikipedia · Entropy